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Three isostructural 3d–4f polynuclear clusters {(LnIII6CoII6)(C8A) 3 } (Ln = Y, Eu, Dy; C8A =  p-tert -butylcalix[8]arene) feature some tripod-like entities in which three Ln 2 -C8A SBUs bolster a [Co 6 ] hexagon.

Constructing [CoII6] hexagon-centered heterometallic {Ln6Co6} (Ln = Y, Eu and Dy) clusters with a calix[8]arene ligand

Constructing [CoII6] hexagon-centered heterometallic {Ln₆Co₆} (Ln = Y, Eu and Dy) clusters with a calix[8]arene ligand