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A C–H iodination reaction of the electron-poor building block, benzo[1,2- b :4,5- b 0]-dithiophene-1,1,5,5-tetraoxide has been reported. This facile functionalization has led to the development of two novel n-type donor–acceptor conjugated polymers.

Facile C–H iodination of electron deficient benzodithiophene-S,S-tetraoxide for the development of n-type polymers