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An epoxy derivative of a naturally occuring vinylphenolic compound, 4-vinylguaiacol, was polymerised using a RAFT/ROCOP strategy and produced ester cross-linked star polymers which could be selectively degraded under acid conditions.

Epoxy-functionalised 4-vinylguaiacol for the synthesis of bio-based, degradable star polymers via a RAFT/ROCOP strategy