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The structure and biocatalytic activities of Au NCs are discussed from the perspective of the ligands, with particular emphasis on the exploration of the undisclosed and neglected roles of shell ligands in the biocatalytic activities of Au NCs.

nanoscale horizons

Ultrasmall Au nanoclusters for bioanalytical and biomedical applications: the undisclosed and neglected roles of ligands in determining the nanoclusters' catalytic activities