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D. A. C. Brownson acknowledges funding from the Ramsay Memorial Fellowships Trust. Funding from the Engineering and Physical Science Research Council (Reference: EP/N001877/1), a British Council Institutional Grant Link (No. 172726574) and Innovate UK (KTP Reference: 11606) is acknowledged.

nanoscale advances

Electrochemical properties of vertically aligned graphenes: tailoring heterogeneous electron transfer through manipulation of the carbon microstructure