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This work investigated the origin of blue PL in undoped and absence of Eu 3+  red PL in the doped Er 2 X 2 O 7  (X = Ti and Zr) pyrochlore using photon, positron and X-ray as spectroscopic probe and further complimenting with DFT.

materials advances

Bright aspects of defects and dark traits of dopants in the photoluminescence of Er2X2O7:Eu3+ (X = Ti and Zr) pyrochlore: an insight using EXAFS, positron annihilation and DFT