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The sterically encumbered cyclopentadienyl ligand 1,2,4-(Me 3 C) 3 C 5 H 2  (Cp′′′) effectively stabilizes the main group metals of Al, Ga, In, Ge and Sn with σ- or π-bonds.

Pentamethyl- and 1,2,4-tri(tert-butyl)cyclopentadienyl containing p-block complexes – differences and similarities