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A new family of {Cu 5 Ln 4 } complexes bearing the dianionic form of pyridine-2,6-dimethanol (pdm 2− ) and ancillary Bu t CH 2 CO 2  −  carboxylate groups is reported and magnetically studied.

dalton transactions

Further synthetic investigation of the general lanthanoid(<scp>iii</scp>) [Ln(<scp>iii</scp>)]/copper(<scp>ii</scp>)/pyridine-2,6-dimethanol/carboxylate reaction system: {CuII5LnIII4} coordination clusters (Ln = Dy, Tb, Ho) and their yttrium(<scp>iii</scp>) analogue

Further synthetic investigation of the general lanthanoid(iii) [Ln(iii)]/copper(ii)/pyridine-2,6-dimethanol/carboxylate reaction system: {CuII5LnIII4} coordination clusters (Ln = Dy, Tb, Ho) and their yttrium(iii) analogue