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A mediated approach for an efficient metal covalent functionalization of the phosphorene surface is presented through the selective insertion of chalcogen atoms. Electronic and steric requirements have been evaluated in details.

On the comparison of oxygen and sulfur transfer reactivities in phosphine and phosphorene: the case of R3Sb(X) carriers (X = O or S)

On the comparison of oxygen and sulfur transfer reactivities in phosphine and phosphorene: the case of R₃Sb(X) carriers (X = O or S)