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New Ru complexes are described that have the potential to interact with DNA in the three ways shown and this may be the reason why some of these complexes have such high antiproliferative activity.

dalton transactions

Cytotoxic (cis,cis-1,3,5-triaminocyclohexane)ruthenium(<scp>ii</scp>)-diphosphine complexes; evidence for covalent binding and intercalation with DNA

Cytotoxic (cis,cis-1,3,5-triaminocyclohexane)ruthenium(ii)-diphosphine complexes; evidence for covalent binding and intercalation with DNA