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Pincer-type tridentate pyridyl bis(pyridylidene amide) (pyPYA 2 ) ligand systems were coordinated to the Earth-abundant first row transition metals nickel, cobalt and zinc, revealing ambidentate  N , N , N  and  O , N , O  coordination behavior.

Ambidentate bonding and electrochemical implications of pincer-type pyridylidene amide ligands in complexes of nickel, cobalt and zinc