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The use of methylalanine in manganese/calcium chemistry has led to the synthesis and characterization of the first manganese/calcium amino acid containing polynuclear clusters.

The first amino acid bound manganese–calcium clusters: a {[MnIII3Ca]2} methylalanine complex, and a [MnIII6Ca] trigonal prism

The first amino acid bound manganese–calcium clusters: a {[MnIII3Ca]₂} methylalanine complex, and a [MnIII6Ca] trigonal prism