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Heterometallic lanthanide-transition metal carbonyl complexes [Sm 2 –Co 2 ], [Yb–Co], and [Sm 2 –Fe 3 ] have been synthesized by redox reactions between bulky amidinate stabilized divalent Ln and TM carbonyl complexes.

3d–4f heterometallic complexes by the reduction of transition metal carbonyls with bulky LnII amidinates

3d–4f heterometallic complexes by the reduction of transition metal carbonyls with bulky Ln^II amidinates