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Under atmospheric conditions, nitrate-RO 2  radicals are equilibrated and react predominantly with HO 2 , RO 2  and NO. The nitrate-RO chemistry is affected strongly by ring closure to epoxy radicals, impeding formation of MVK/MACR.

Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene

Theoretical and experimental study of peroxy and alkoxy radicals in the NO₃-initiated oxidation of isoprene