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The higher-energy  cis - as well as the global minimum  trans -rotamers of the four H/D isotopologues of the formic acid monomer have been examined with Raman jet spectroscopy extending the vibrational gas phase reference database by eleven new  cis -band positions for HCOOD, DCOOH, and DCOOD.

physical chemistry chemical physics/pccp. physical chemistry chemical physics

Increasing the weights in the molecular work-out of cis- and trans-formic acid: extension of the vibrational database via deuteration