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Infrared photodissociation spectra of microhydrated sulfate dianions with three to eight water molecules are presented over a broad spectral range that covers intramolecular solvent and solute modes as well as intermolecular librational modes.

Cryogenic ion trap vibrational spectroscopy of the microhydrated sulfate dianions SO42−(H2O)3−8

Cryogenic ion trap vibrational spectroscopy of the microhydrated sulfate dianions SO₄²⁻(H₂O)₃₋₈