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The accuracy of variationally calculated vibrational levels of ozone can be greatly improved by adding diagonal Born–Oppenheimer correction to the best available  ab initio  potential.

physical chemistry chemical physics/pccp. physical chemistry chemical physics

Diagonal Born–Oppenheimer corrections to the ground electronic state potential energy surfaces of ozone: improvement of ab initio vibrational band centers for the 16O3, 17O3 and 18O3 isotopologues