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The properties of the mixed system LiBH4 LiCl P2S5 are studied with respectto all-solid-state batteries. The studied material undergoes an amorphizationupon heating above 601C, accompanied with increased Li+ conductivity beneficialfor battery electrolyte applications. The measured ionic conductivity is 10-3Scm-1 at room temperature with an activation energy of 0.40(2) eV afteramorphization. Structural analysis and characterization of the material suggestthat BH4 groups and PS4 may belong to the same molecular structure, where Clions interplay to accommodate the structural unit. Thanks to its conductivity,ductility and electrochemical stability (up to 5 V, Au vs. Li+/Li), this newelectrolyte is successfully tested in battery cells operated with a cathodematerial (layered TiS2, theo. capacity 239 mAh g-1) and Li anode resulting in93% capacity retention (10 cycles) and notable cycling stability under thecurrent density 12 mA g-1 (0.05C-rate) at 501C. Further advancedcharacterisation by means of operando synchrotron X-ray diffraction intransmission mode contributes explicitly to a better understanding of the(de)lithiation processes of solid-state battery electrodes operated at moderatetemperatures.

Pseudo-ternary LiBH4-LiCl-P2S5 system as structurally disordered bulk electrolyte for all-solid-state lithium batteries