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[{Re I (CO) 3 (Hbim)} 3 (tpta)] 2  (1, Hbim −  = 2,2′-biimidazolate monoanion, tpta = 2,4,6-tripyridyl-1,3,5-triazine) was prepared as a nano-space supramolecule by using a new group of H-bonded coordination capsules.

Gas sorption of nano-porous supramolecules formed by multi-hydrogen bonded coordination capsules