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A highly selective metal-free CDC approach for the synthesis of 1-indolyltetrahydro-β-carbolines is developed. The total synthesis of biologically important alkaloids, eudistomin U and isoeudistomin U and the first total synthesis of 19-bromoisoeudistomin U were accomplished.

chemical communications

Access to 1-indolyltetrahydro-β-carbolines <i>via</i> metal-free cross-dehydrogenative coupling: the total synthesis of eudistomin U, isoeudistomin U and 19-bromoisoeudistomin U

Access to 1-indolyltetrahydro-β-carbolines via metal-free cross-dehydrogenative coupling: the total synthesis of eudistomin U, isoeudistomin U and 19-bromoisoeudistomin U