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2,5-Dimethylfuran is deoxygenated to n-hexane with 100% yield on a bifunctional Pt/C-Cs 2.5 H 0.5 PW 12 O 40 catalyst under very mild conditions (90 °C, 1 bar H 2 ) in a one-step gas-phase process. A proposed mechanism includes a sequence of hydrogenolysis, hydrogenation and dehydration steps occurring on Pt and proton sites of the bifunctional catalyst.

chemical communications

Facile gas-phase hydrodeoxygenation of 2,5-dimethylfuran over bifunctional metal-acid catalyst Pt–Cs2.5H0.5PW12O40