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Assessment of the solution equilibria of [bis(pyridine)iodine( i )] + complexes by ESI-MS and NMR reveals a statistical ligand distribution across the iodine( i ) centres with a preference to form complexes with a more basic pyridine.

Asymmetric [N–I–N]+halonium complexes in solution?

Asymmetric [N–I–N]⁺halonium complexes in solution?