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The hydrophosphination of activated alkenes and internal alkynes is reported using a remarkably simple Ge( iv ) pre-catalyst. Preliminary mechanistic investigations indicate that the reaction proceeds  via  a redox neutral catalytic cycle.

Hydrophosphination using [GeCl{N(SiMe3)2}3] as a pre-catalyst

Hydrophosphination using [GeCl{N(SiMe₃)₂}₃] as a pre-catalyst