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The π-conjugation of an electroactive perchlorotriphenylmethyl (PTM˙) radical to an  E / Z  switchable stilbene derivative permits to demonstrate that its electrocatalytic  Z  →  E  isomerization is undoubtedly triggered by the open-shell nature of PTM˙ unit.

Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical