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Reported herein is the coordination of rhenium complexes to tetrazine ligand in [ReCl(CO) 3 (TzPy)] [ 1 ] (TzPy = 3-(2-pyridyl)-1,2,4,5-tetrazine) and the rates of addition of different dienophiles to the tetrazine.

Tetrazine metallation boosts rate and regioselectivity of inverse electron demand Diels–Alder (iEDDA) addition of dienophiles