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We report on the ( tert -butyl)isocyanide-catalysed isomersation of a phosphaethynolato-borane, [B]OCP, to its linkage isomer, a phosphaketenyl-borane, [B]PCO.

chemical science

Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene