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Highly enantioselective CuAAC reactions for the synthesis of versatile  P -chiral phosphorus synthons featuring a versatile ethynyl group were developed.

chemical science

Enantioselective synthesis of <i>P</i>-chiral tertiary phosphine oxides with an ethynyl group <i>via</i> Cu(<scp>i</scp>)-catalyzed azide–alkyne cycloaddition

Enantioselective synthesis of P-chiral tertiary phosphine oxides with an ethynyl group via Cu(i)-catalyzed azide–alkyne cycloaddition