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Emulsification of elemental mercury in aqueous solution in the form of grey particles occurs upon exposure to intense sound fields. We show the concomitant formation of molecular Hg(OH) 2 in the solution phase reaching a saturation limit of 0.24 mM at 25 °C. The formation of Hg(OH) 2 is consistent with the 'hot spot' model which suggests the formation of OH˙ as a result of acoustic cavitation; such radicals are proposed to combine with Hg to form the Hg(OH) 2 species here characterised using voltammetry.

Acoustic cavitation generates molecular mercury(ii) hydroxide, Hg(OH)2, from biphasic water/mercury mixtures

Acoustic cavitation generates molecular mercury(ii) hydroxide, Hg(OH)₂, from biphasic water/mercury mixtures