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Control over the composition and nanostructure of solid electrocatalysts is quite important for drastic improvement of their performance. The cation exchange reaction of nanocrystals (NCs) has been reported as the way to provide metastable crystal structures and complicated functional nanostructures that are not accessible by conventional synthetic methods. Herein we demonstrate the cation exchange-derived formation of metastable spinel Ni 3 Se 4 NCs (sp-Ni 3 Se 4 ) and phase segregated berzelianite Cu 2- x  Se (ber-Cu 2- x  Se)/sp-Ni 3 Se 4 heterostructured NCs as active oxygen evolution reaction (OER) catalysts. A rare sp-Ni 3 Se 4 phase was formed by cation exchange of ber-Cu 2- x  Se NCs with Ni 2+ ions, because both phases have the face-centered cubic (fcc) Se anion sublattice. Tuning the Ni : Cu molar ratio leads to the formation of Janus-type ber-Cu 2- x  Se/sp-Ni 3 Se 4 heterostructured NCs. The NCs of sp-Ni 3 Se 4 and ber-Cu 2- x  Se/sp-Ni 3 Se 4 heterostructures exhibited high catalytic activities in the OER with small overpotentials of 250 and 230 mV at 10 mA cm -2 in 0.1 M KOH, respectively. They were electrochemically oxidized during the OER to give hydroxides as the real active species. We anticipate that the cation exchange reaction could have enormous potential for the creation of novel heterostructured NCs showing superior catalytic performance.

chemical science

Phase segregated Cu2−xSe/Ni3Se4 bimetallic selenide nanocrystals formed through the cation exchange reaction for active water oxidation precatalysts