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Cationic tetrahedra: condensed phase access to the tetrahedral cations [EP 3 ] +  (E = S, Se, Te) isoelectronic to P 4  or AsP 3  was found by the reactions of ECl 3 [WCA] with P 4  ([WCA] −  = [Al(OR F ) 4 ] −  and [F(Al(OR F ) 3 ) 2 ] − ; –R F  = –C(CF 3 ) 3 ).

First experimental evidence for the elusive tetrahedral cations [EP3]+ (E = S, Se, Te) in the condensed phase

First experimental evidence for the elusive tetrahedral cations [EP₃]⁺ (E = S, Se, Te) in the condensed phase