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Supporting two metal binding sites by a tailored polydentate trop-based (trop = 5 H -dibenzo[ a , d ]cyclohepten-5-yl) ligand yields highly unsymmetric homobimetallic rhodium( i ) complexes. These were studied as models for Rh/C hydrogenation catalysts.

Low-valent homobimetallic Rh complexes: influence of ligands on the structure and the intramolecular reactivity of Rh–H intermediates