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A Pd/Cu catalyst-controlled regiodivergent and stereospecific ring-opening C(sp 3 )–Si cross-coupling of 2-arylaziridines with silylborane has been developed and a new tandem reaction to give another regioisomer of silylamine has been discovered.

chemical science

Catalyst-controlled regiodivergent ring-opening C(sp<sup>3</sup>)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis

Catalyst-controlled regiodivergent ring-opening C(sp3)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis

Catalyst-controlled regiodivergent ring-opening C(sp³)–Si bond-forming reactions of 2-arylaziridines with silylborane enabled by synergistic palladium/copper dual catalysis