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Herein, we report three-component vicinal-diarylation of non-conjugated alkenes initiated by transmetalation of arylboronic acids, which provides complementary access to β,γ-diaryl carbonyl compounds. We have also screened a large number of chiral ligands for developing an enantioselective version of this reaction and obtained the preliminary results (up to 79 : 21 e.r.). Notably, the methodology developed herein represents the first three component syn -vicinal-dicarbofunctionalization of non-conjugated alkenes involving palladium catalysis.

Three-component vicinal-diarylation of alkenes via direct transmetalation of arylboronic acids