English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Coordinatively unsaturated Mo(iii) complexes have been identified as highly reactive species able to activate dinitrogen without the need for a sacrificial reducing agent. Here, we report a coordinatively saturated octahedral Mo(iii) complex stabilized by κ 2 -tris( tert -butoxy)silanolate ligands, which is yet highly reactive towards dinitrogen and small molecules. The combined high stability and activity are ascribed to the dual binding mode of the tris( tert -butoxy)silanolate ligands that allow unlocking a coordination site in the presence of reactive small molecules to promote their activation at low temperatures.

A reactive coordinatively saturated Mo(iii) complex: exploiting the hemi-lability of tris(tert-butoxy)silanolate ligands