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We report the selective insertion of a range of borylene fragments into the E-E bonds (E = S, Se, Te) of cyclic boron dichalcogenides. This method provides facile synthetic access to a variety of symmetrical and unsymmetrical four- and five-membered rings.

Synthesis of unsymmetrical B2E2 and B2E3 heterocycles by borylene insertion into boradichalcogeniranes

Synthesis of unsymmetrical B₂E₂ and B₂E₃ heterocycles by borylene insertion into boradichalcogeniranes