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PMMA-based copolymer containing aryl TFVE moieties prepared by copolymerization of MMA and TFVOPMA monomer containing aryl TFVE group and thermal cross-linked by [2π + 2π] cycloaddition reaction of aryl TFVE moieties.

rsc advances

Crosslinked poly(methyl methacrylate) with perfluorocyclobutyl aryl ether moiety as crosslinking unit: thermally stable polymer with high glass transition temperature