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We report a novel catalyst Pd/SOS that catalyzes the dual C–C bond forming coupling of an iodoarene moiety with an internal alkene and an external alkyne  via  an intramolecular Heck reaction, followed by an intermolecular Sonogashira reaction, respectively.

Novel ultra-small Pd NPs on SOS spheres: a new catalyst for domino intramolecular Heck and intermolecular Sonogashira couplings