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Alkaline earth metal substitutions on the A-site of pyrochlore oxide M x La 2−x Ce 1.8 Ru 0.2 O 7−δ  (M = Mg, Ca) were studied as catalyst materials for oxidative/autothermal steam reforming of ethanol (OSRE/ATR).

rsc advances

Oxidative steam reforming of ethanol over MxLa2−xCe1.8Ru0.2O7−δ (M = Mg, Ca) catalysts: effect of alkaline earth metal substitution and support on stability and activity