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The near infrared reflectivity and black color tone of a Ca 2 Mn 0.85 Ti 0.15 O 4  pigment were improved by the introduction of strain with Zn 2+  doping into the [MnO 6 ] octahedra and a decrease in the manganese ion concentration.

rsc advances

Improvement of near-infrared (NIR) reflectivity and black color tone by doping Zn2+ into the Ca2Mn0.85Ti0.15O4 structure