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An efficient method of synthesizing 2-trifluoromethylindoles from indoles with easy-to-handle, cheap and low-toxic CF 3 SO 2 Na under metal-free conditions is described, which selectively introduces trifluoromethyl to indoles on the C2 position.

Metal-free oxidative trifluoromethylation of indoles with CF3SO2Na on the C2 position

Metal-free oxidative trifluoromethylation of indoles with CF₃SO₂Na on the C2 position