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Polyoxymethylene dimethyl ethers were successfully synthesized from acetalation under the catalysis of novel polymeric acidic ionic liquids (PAILs). PAILs copolymerized by divinylbenzene with ILs displayed exceptional catalytic efficiencies.

rsc advances

Novel polymeric acidic ionic liquids as green catalysts for the preparation of polyoxymethylene dimethyl ethers from the acetalation of methylal with trioxane