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Four new hetero-pentanuclear 3d–4f complexes  1–4  were synthesized and characterized. Supramolecular interactions and fluorescence properties of complexes  1–4  were investigated.

rsc advances

Four rare structurally characterized hetero-pentanuclear [Zn<sub>4</sub>Ln] bis(salamo)-type complexes: syntheses, crystal structures and spectroscopic properties

Four rare structurally characterized hetero-pentanuclear [Zn4Ln] bis(salamo)-type complexes: syntheses, crystal structures and spectroscopic properties

Four rare structurally characterized hetero-pentanuclear [Zn₄Ln] bis(salamo)-type complexes: syntheses, crystal structures and spectroscopic properties