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Tetragonal Cu 2 SnS 3  and orthorhombic Cu 4 SnS 4  nanocubes were synthesized by a heat up procedure with oleylamine (OLA) and dodecanethiol (DT) acting as both solvent and capping ligands.

rsc advances

Phase transition in Cu2+xSnS3+y(0 ≤x≤ 2; 0 ≤y≤ 1) ternary systems synthesized from complexes of coumarin derived thiocarbamate motifs: optical and morphological properties