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New 3-coordinated Zn ROP catalysts afford lactide stereo-block copolymers with variable block lengths and steric structures and diblock ε-caprolactone-lactide copolymers at room temperature and in short reaction times.

rsc advances

Tailor-made block copolymers of <scp>l</scp>-, <scp>d</scp>- and <i>rac</i>-lactides and ε-caprolactone <i>via</i> one-pot sequential ring opening polymerization by pyridylamidozinc(<scp>ii</scp>) catalysts

Tailor-made block copolymers of l-, d- and rac-lactides and ε-caprolactone via one-pot sequential ring opening polymerization by pyridylamidozinc(ii) catalysts