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We present a seed-mediated approach to generate Au@PtCu nanostars with a five-fold twinned structure. The Au@PtCu nanostars exhibited better electrocatalytic properties in terms of activity and stability toward MOR relative to commercial Pt/C.

Seed-mediated synthesis of Au@PtCu nanostars with rich twin defects as efficient and stable electrocatalysts for methanol oxidation reaction