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PGS–APTES–Pd(OAc) 2  was prepared through simple and green steps from the natural clay mineral palygorskite. Obviously, the stability and reusability of PGS–APTES–Pd(OAc) 2  were superior to those of the PGS–Pd catalyst (prepared by the impregnation method) in recycling test.

Palygorskite-anchored Pd complexes catalyze the coupling reactions of pyrimidin-2-yl sulfonates