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The as-prepared 4HQ-rGO/Cu 2+  sensor possessed a high response, outstanding selectivity and fast response-recovery characteristic, which was mainly attributed to the supramolecularly assemble of 4-hydroxyquinoline, and Cu 2+  with graphene nanosheets.

Assembly with copper(ii) ions and D–π–A molecules on a graphene surface for ultra-fast acetic acid sensing at room temperature