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Three classes of organosilicas (DMO, OMOs and PMOs) containing immobilized multi-hydroxyl bis-(quaternary ammonium) iodide salts were prepared and tested in the cycloaddition of CO 2 and epoxides. Owing to its higher surface area, pore volume and optimum nucleophilicity of the iodide ion, OMO-2 with two hydroxyl groups was found to be the most active catalyst. For substrates that are easy to activate such as propylene oxide, 1,2-epoxybutane and epichlorohydrin, excellent yields and selectivities were obtained under mild reaction conditions (0.5 MPa CO 2 , 50 °C and 10-15 h). Moreover, OMO-2 showed very good catalytic properties (yield ≥ 93% and selectivity ≥ 98%), and excellent chemical and textural stability in the synthesis of 1,2-butylene carbonate over 5 cycles.

Novel porous organocatalysts for cycloaddition of CO2 and epoxides

Novel porous organocatalysts for cycloaddition of CO₂ and epoxides