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An efficient Rh-catalyzed arylation of  N -tosylarylimines has been developed with benzene backbone sulfoxide–olefin ligands, affording chiral diarylmethylamines in high yields (up to 99%) with excellent enantioselectivities (up to 99% ee).

rsc advances

Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to <i>N</i>-tosylarylimines

Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines