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In this study, novel hydroxyl-terminated polybutadiene (HTPB) with a high  cis -1,4 content was developed using a  tert -butyl dimethyl siloxy dimethyl propyl lithium (Li)–naphthenate nickel (Ni)–boron trifluoride (B) initiating system (Li–Ni–B).

rsc advances

A novel synthetic strategy for hydroxyl-terminated polybutadiene containing high <i>cis</i>-1,4 contents based on a Ni(<scp>ii</scp>)-coordinated anionic initiating system

A novel synthetic strategy for hydroxyl-terminated polybutadiene containing high cis-1,4 contents based on a Ni(ii)-coordinated anionic initiating system